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style="font-size:12px;font-family:'Arial','sans-serif';color:#3366CC">?</span></sup><span style="font-size:1px;font-family:'Arial','sans-serif';color:#136EC2">?</span></p><p style="line-height: 24px"><br/></p><p style="line-height: 24px"><span style="font-size:22px;font-family:'微軟雅黑','sans-serif';color:black">工作原理</span></p><p style="line-height: 24px"><br/></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">工作原理就是離子的交換。</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">運行時(shí)：陽(yáng)樹(shù)脂</span><span style="font-family: Arial, sans-serif">(H-R)+(M</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup><span style="font-family: Arial, sans-serif">)→(M-R)+(H</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup><span style="font-family: Arial, sans-serif">)</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">陰樹(shù)脂</span><span style="font-family: Arial, sans-serif">(OH-R)+(X</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: Arial, sans-serif">)→(X-R)+(OH</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: Arial, sans-serif">)</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">其中</span><span style="font-family: Arial, sans-serif">M</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup><span style="font-family: 宋體">為金屬離子，</span><span style="font-family: Arial, sans-serif">X</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: 宋體">為陰離子。再生過(guò)程為其逆過(guò)程。</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">離子交換器的失效控制</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">離子交換除鹽水處理最簡(jiǎn)單的流程為陽(yáng)床</span><span style="font-family: Arial, sans-serif">-</span><span style="font-family: 宋體">陰床組成的一級復床除鹽系統。有的一級</span><span style="font-family: Arial, sans-serif"><span style="font-family: 宋體;color: rgb(19, 110, 194)">復床</span></span><span style="font-family: 宋體">除鹽系統采用單元制，即每套一級復床除鹽系統包括</span> <span style="font-family: 宋體">陽(yáng)床、（除碳器）、陰床各一臺，在離子交換除鹽運行過(guò)程中，無(wú)論是陽(yáng)床還是陰床先失效，都是同時(shí)再生；還有的一級復床除鹽系統采用母管制，即陽(yáng)床與陽(yáng)床或陰床與陰床是并聯(lián)運行的，哪一臺交換器失效就再生哪一臺。</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: Arial, sans-serif">1 </span><span style="font-family: 宋體">檢測和控制原理</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">強酸性陽(yáng)樹(shù)脂對水中各種陽(yáng)離子的吸附順序為：</span><span style="font-family: Arial, sans-serif">Fe</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">3+</span></sup><span style="font-family: Arial, sans-serif">>Al</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">3+</span></sup><span style="font-family: Arial, sans-serif">>Ca</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">2+</span></sup><span style="font-family: Arial, sans-serif">>Mg</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">2+</span></sup><span style="font-family: Arial, sans-serif">>Na</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup><span style="font-family: Arial, sans-serif">>H</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup><sup><span style="font-size: 12px;font-family: 宋體">；</span></sup><span style="font-family: 宋體">由此可知，水中金屬離子</span><span style="font-family: Arial, sans-serif">Na</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup><span style="font-family: 宋體">被吸附的能力最弱，所以當離子交換時(shí)樹(shù)脂層的各種</span><span style="font-family: Arial, sans-serif"><span style="font-family: 宋體;color: rgb(19, 110, 194)">離子吸附</span></span><span style="font-family: 宋體">層逐漸下移，</span><span style="font-family: Arial, sans-serif">H</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+.</span></sup><span style="font-family: 宋體">最后被其他陽(yáng)離子置換下來(lái)，當保護層穿透時(shí)，首先泄漏的是最下層的</span><span style="font-family: Arial, sans-serif">Na</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup><span style="font-family: 宋體">；因此監督陽(yáng)離子交換器失效是以漏鈉為標準的；其反應方程為（</span><span style="font-family: Arial, sans-serif">A</span><span style="font-family: 宋體">代表金屬陽(yáng)離子</span><span style="font-family: Arial, sans-serif">,R</span><span style="font-family: 宋體">為樹(shù)脂基團）：</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: Arial, sans-serif">A</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">n+</span></sup><span style="font-family: Arial, sans-serif">+nRH=R</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">n</span></sub><span style="font-family: Arial, sans-serif">A+nH</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: Arial, sans-serif">HCO</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">3</span></sub><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: Arial, sans-serif">+ H</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">+</span></sup><sup><span style="font-size: 12px;font-family: Arial, sans-serif">?</span></sup><span style="font-family: Arial, sans-serif">=H</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">2</span></sub><span style="font-family: Arial, sans-serif">O+CO</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">2</span></sub><span style="font-family: Arial, sans-serif">↑</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">強堿性陰樹(shù)脂對水中各種陰離子的吸附順序為：</span><span style="font-family: Arial, sans-serif">SO</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">4</span></sub><sup><span style="font-size: 12px;font-family: Arial, sans-serif">2-</span></sup><span style="font-family: Arial, sans-serif">>NO</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">3</span></sub><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: Arial, sans-serif">>Cl</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: Arial, sans-serif">>OH</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: Arial, sans-serif">>HCO</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">3</span></sub><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: Arial, sans-serif">>HSiO</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">3</span></sub><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><sup><span style="font-size: 12px;font-family: Arial, sans-serif">?</span></sup><span style="font-family: 宋體">。由此可知，</span><span style="font-family: Arial, sans-serif">HSiO</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">3</span></sub><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: 宋體">的吸附能力最弱，所以當離子交換時(shí)樹(shù)脂層的各種離子吸附層逐漸下移，</span><span style="font-family: Arial, sans-serif">OH</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-.</span></sup><span style="font-family: 宋體">被其他陰離子置換下來(lái)，當保護層穿透時(shí)，首先泄漏的是最下層的</span><span style="font-family: Arial, sans-serif">HSiO</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">3</span></sub><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup><span style="font-family: 宋體">；因此監督陰離子交換器失效是以漏硅為標準的；其反應方程為（</span><span style="font-family: Arial, sans-serif">B</span><span style="font-family: 宋體">代表酸根陰離子，</span><span style="font-family: Arial, sans-serif">R</span><span style="font-family: 宋體">為樹(shù)脂基團）：</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: Arial, sans-serif">B</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">m-</span></sup><span style="font-family: Arial, sans-serif">+mROH=R</span><sub><span style="font-size: 12px;font-family: Arial, sans-serif">m</span></sub><span style="font-family: Arial, sans-serif">B+mOH</span><sup><span style="font-size: 12px;font-family: Arial, sans-serif">-</span></sup></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: Arial, sans-serif">2 </span><span style="font-family: 宋體">控制點(diǎn)和控制方法</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">由于母管制系統包含了單元制系統</span><span style="font-family: Arial, sans-serif">,</span><span style="font-family: 宋體">而且它具有能充分使用樹(shù)脂、提高交換器的出水能力、降低酸堿消耗等優(yōu)點(diǎn)，我們在研究中主要討論以這種結構為基礎的離子交換除鹽水處理系統。</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">以成都生物制品研究所蛋白分離車(chē)間純水站為例，該系統為母管制水處理系統，系統的結構為：砂濾</span><span style="font-family: Arial, sans-serif">-</span><span style="font-family: 宋體">活性炭過(guò)濾</span><span style="font-family: Arial, sans-serif">-</span><span style="font-family: 宋體">粗濾</span><span style="font-family: Arial, sans-serif">-</span><span style="font-family: 宋體">陽(yáng)床</span><span style="font-family: Arial, sans-serif">- </span><span style="font-family: 宋體">一陰</span><span style="font-family: Arial, sans-serif">-</span><span style="font-family: 宋體">二陰</span><span style="font-family: Arial, sans-serif">-</span><span style="font-family: 宋體">混床</span><span style="font-family: Arial, sans-serif">-</span><span style="font-family: 宋體">精濾</span><span style="font-family: Arial, sans-serif">-</span><span style="font-family: 宋體">純水罐，系統產(chǎn)水能力為</span><span style="font-family: Arial, sans-serif">5t/h</span><span style="font-family: 宋體">，在系統的失效控制研究中，我們提出單元失效控制概念，也就是充分利用了母管制制水系統的優(yōu)點(diǎn)對系統進(jìn)行失效控制。</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">（</span><span style="font-family: Arial, sans-serif">1</span><span style="font-family: 宋體">）</span><span style="font-family: Arial, sans-serif">RO</span><span style="font-family: 宋體">對各有機溶質(zhì)的去除率大于</span><span style="font-family: Arial, sans-serif">NF</span><span style="font-family: 宋體">膜。（</span><span style="font-family: Arial, sans-serif">2</span><span style="font-family: 宋體">）不同有機溶質(zhì)的去除率不相同，有的甚至相差很大（例如，</span><span style="font-family: Arial, sans-serif">RO</span><span style="font-family: 宋體">和</span><span style="font-family: Arial, sans-serif">NF</span><span style="font-family: 宋體">膜對乙酸的吸光度去除率分別為</span><span style="font-family: Arial, sans-serif">95.34%</span><span style="font-family: 宋體">、</span><span style="font-family: Arial, sans-serif">81.45%</span><span style="font-family: 宋體">，而對</span><span style="font-family: Arial, sans-serif"><span style="font-family: 宋體;color: rgb(19, 110, 194)">苯胺</span></span><span style="font-family: 宋體">的吸光度去除率則分別為</span><span style="font-family: Arial, sans-serif">61.50%</span><span style="font-family: 宋體">、</span><span style="font-family: Arial, sans-serif">46.82%</span><span style="font-family: 宋體">）。</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: Arial, sans-serif">3 </span><span style="font-family: 宋體">出水水質(zhì)</span></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">原水經(jīng)一級復床除鹽后，電導率（</span><span style="font-family: Arial, sans-serif">25</span><span style="font-family: 宋體">℃</span><span style="font-family: 宋體">）低于</span><span style="font-family: Arial, sans-serif">10μS/cm</span><span style="font-family: 宋體">，水中硅含量低于</span><span style="font-family: Arial, sans-serif">100μg/L</span><span style="font-family: 宋體">。</span></p><p style="line-height: 24px"><span style="font-size:22px;font-family:'微軟雅黑','sans-serif';color:black">用途</span></p><p style="line-height: 24px"><br/></p><p style="text-indent: 32px;line-height: 24px"><span style="font-family: 宋體">離子交換器主要用于純水和高純水的制備，在醫藥、化工、電子、涂裝、飲料及中高壓鍋爐給水等諸多工領(lǐng)域中已有十分廣泛的應用。用于鍋爐、熱電站、化工、輕工、紡織、醫藥、生物、電子、原子能及純水處理的前道處理，工業(yè)生產(chǎn)所需進(jìn)行</span><span style="font-family: Arial, sans-serif"><span style="font-family: 宋體;color: rgb(19, 110, 194)">硬水軟化</span></span><span style="font-family: 宋體">、去離子水制備的場(chǎng)合，還可用于食品藥物的脫色提純，貴重金屬、化工原料的回收，電鍍廢水的處理等。</span></p><p>?</p><p><br/></p> </section> <section class="tab-pane met-editor clearfix animation-fade " id="product-content1"> </section> <section class="tab-pane met-editor clearfix animation-fade " id="product-content2"> 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